|
|
H2O + chlorogenic_acid <=> caffeic_acid + quinate + H+
|
3.1.1.20
tannase
3.1.1.42
chlorogenate hydrolase
3.1.1.73
feruloyl esterase
|
–
–
–
|
M
|
|
BRENDA:
BR10661
KEGG:
R02997
MetaCyc:
CHLOROGENATE-HYDROLASE-RXN
|
|
|
|
caffeic_acid + O2 <=> H+ + 3-(2-carboxyethenyl)-cis,cis-muconate
|
1.13.11.22
caffeate 3,4-dioxygenase
|
–
|
K
|
|
BRENDA:
BR40483
KEGG:
R03365
MetaCyc:
CAFFEATE-34-DIOXYGENASE-RXN
|
|
|
|
S-adenosyl-L-methionine + caffeic_acid <=> H+ + ferulic_acid + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
2.1.1.68
caffeate O-methyltransferase
|
–
–
|
MK
|
|
BRENDA:
BR43911
KEGG:
R03366
MetaCyc:
RXN-1104
SABIO-RK:
14976
|
|
|
|
3,4-dihydroxyphenylpropanoyl-CoA + caffeic_acid <=> 3,4-Dihydroxyphenylpropionate + caffeoyl-CoA
|
2.8.3.23
caffeate CoA-transferase
|
–
|
|
|
BRENDA:
BR51451
KEGG:
R11206
MetaCyc:
RXN-16745
|
|
|
|
caffeic_acid + CoA + ATP <=> caffeoyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
|
–
|
BMK
|
|
BRENDA:
BS26
KEGG:
R01943
MetaCyc:
RXN-1126
SABIO-RK:
12842;
1996
|
|
|
|
p-coumaric_acid + O2 + FADH2 <=> caffeic_acid + H2O + FAD + H+
|
1.14.14
1.14.14.9
4-hydroxyphenylacetate 3-monooxygenase
|
–
–
|
M
|
|
BRENDA:
BS428032
MetaCyc:
RXN-14988
|
|
|
|
caffeic_acid + H+ <=> 3,4-Dihydroxystyrene + CO2
|
4.1.1.102
phenacrylate decarboxylase
|
–
|
K
|
|
BRENDA:
BS433533
KEGG:
R03367
MetaCyc:
RXN-21078
SABIO-RK:
12041
|
|
|
|
L-Dopa <=> caffeic_acid + NH3
|
4.3.1.23
tyrosine ammonia-lyase
4.3.1.25
phenylalanine/tyrosine ammonia-lyase
|
–
–
|
M
|
|
BRENDA:
BS445601
MetaCyc:
RXN-14987
|
|
|
|
trans-5-O-caffeoylshikimate + H2O <=> caffeic_acid + shikimate
|
3.1.1
3.1.1.42
chlorogenate hydrolase
|
–
–
|
K
|
|
BRENDA:
BS447258
KEGG:
R10701
|
|
|
|
methyl_caffeate + H2O <=> caffeic_acid + methanol
|
3.1.1.42
chlorogenate hydrolase
3.1.1.73
feruloyl esterase
|
–
–
|
|
|
BRENDA:
BS139695
SABIO-RK:
7118
|
|
|
|
UDP-glucose + caffeic_acid <=> UDP + 1-O-caffeoyl-beta-D-glucose
|
2.4.1.120
sinapate 1-glucosyltransferase
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
2.4.1.177
cinnamate beta-D-glucosyltransferase
|
–
–
–
|
|
|
BRENDA:
BS322022
SABIO-RK:
14463
|
|
|
|
UDP-glucose + caffeic_acid <=> UDP + caffeoyl_3-O-beta-D-glucoside
|
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
2.4.1.35
phenol beta-glucosyltransferase
|
–
–
|
|
|
BRENDA:
BS378012
SABIO-RK:
13059
|
|
|
|
p-coumaric_acid + O2 + caffeic_acid <=> caffeic_acid + H2O + (2E)-3-(3,4-dioxocyclohexa-1,5-dien-1-yl)prop-2-enoic_acid
|
1.14.18.1
tyrosinase
|
–
|
|
|
KEGG:
R02950
|
|
|
|
p-coumaric_acid <=> caffeic_acid
|
1.14.13
|
–
|
K
|
|
KEGG:
R07826
|
|
|
|
p-coumaric_acid + reduced_[NADPH-hemoprotein_reductase] + O2 <=> caffeic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
M
|
|
MetaCyc:
RXN-1103
|
|
|
|
ground_state_fungal_oxyluciferin + H2O <=> caffeic_acid + pyruvate + H+
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-19086
|
|
|
|
caffeic_acid + light <=> (2Z)-3-(3,4-dihydroxyphenyl)prop-2-enoic_acid
|
5.2.1
|
–
|
|
|
MetaCyc:
RXN-8336
|
|
|
|
caffeic_acid + O2 <=> (2E)-3-(3,4-dioxocyclohexa-1,5-dien-1-yl)prop-2-enoic_acid + H2O
|
1.10.3.1
catechol oxidase
1.14.18.1
tyrosinase
|
–
–
|
|
|
BRENDA:
BS289477
|
|
|
|
caffeic_acid + FADH2 + O2 <=> 3,4,5-trihydroxycinnamic_acid + FAD + H2O
|
1.14.14.9
4-hydroxyphenylacetate 3-monooxygenase
|
–
|
|
|
BRENDA:
BS443257
|
|
|
|
Caffeoylcholine <=> caffeic_acid + choline
|
3.1.1.49
sinapine esterase
|
–
|
|
|
BRENDA:
BS64557
|
|
|
|
dimethylallyl_diphosphate + caffeic_acid <=> diphosphate + 3-O,4-O-bis-(dimethylallyl)caffeate
|
2.5.1.111
4-hydroxyphenylpyruvate 3-dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS423348
|
|
|
|
dimethylallyl_diphosphate + caffeic_acid <=> diphosphate + 3-O-(dimethylallyl)caffeate
|
2.5.1.111
4-hydroxyphenylpyruvate 3-dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS423349
|
|
|
|
dimethylallyl_diphosphate + caffeic_acid <=> diphosphate + 4-O-(dimethylallyl)caffeate
|
2.5.1.111
4-hydroxyphenylpyruvate 3-dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS423350
|
|
|
|
3-hydroxycinnamic_acid + reduced_flavodoxin + O2 <=> caffeic_acid + flavin + H2O
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
|
|
BRENDA:
BS386814
|
|
|
|
p-coumaric_acid + O2 + reduced_acceptor <=> caffeic_acid + H2O + A
|
1.14.18.1
tyrosinase
1.14.99.15
4-methoxybenzoate monooxygenase (O-demethylating)
|
–
–
|
|
|
BRENDA:
BS353328
|
|
|
|
2 S-adenosyl-L-methionine + caffeic_acid <=> 2 S-adenosyl-L-homocysteine + ferulic_acid + isoferulic_acid
|
2.1.1.336
norbelladine O-methyltransferase
|
–
|
|
|
BRENDA:
BS454839
|
|
|
|
1-O-caffeoyl-beta-D-glucose + cyanidin_3-O-beta-D-glucoside <=> caffeic_acid + cyanidin_3,5-di-O-beta-D-glucoside
|
2.4.1.299
cyanidin 3-O-glucoside 5-O-glucosyltransferase (acyl-glucose)
|
–
|
|
|
BRENDA:
BS422276
|
|
|
|
rosmarinic_acid + H2O <=> caffeic_acid + 3,4-dihydroxyphenyllactic_acid
|
3.1.1.20
tannase
|
–
|
|
|
BRENDA:
BS417575
|
|
|
|
1-O-caffeoyl-beta-D-glucose + cyanidin_3-O-beta-D-glucoside <=> caffeic_acid + cyanidin_3,7-di-O-beta-D-glucoside
|
2.4.1.300
cyanidin 3-O-glucoside 7-O-glucosyltransferase (acyl-glucose)
|
–
|
|
|
BRENDA:
BS422277
|
|
|
|
rutin + caffeic_acid <=> quercetin + caffeic_acid_3''-O-rutinoside
|
3.2.1.168
hesperidin 6-O-alpha-L-rhamnosyl-beta-D-glucosidase
|
–
|
|
|
BRENDA:
BS450562
|
|
|
|
p-coumaric_acid + O2 <=> caffeic_acid + H2O
|
1.14.18.1
tyrosinase
|
–
|
|
|
BRENDA:
BS406274
|
|
|
|
chlorogenic_acid + H2O <=> caffeic_acid + (1S,3R,4R)-1,3,4,5-tetrahydroxycyclohexane-1-carboxylic_acid
|
3.1.1.B10
|
–
|
|
|
BRENDA:
BS446874
|
|
|
|
sucrose + caffeic_acid <=> D-fructose + 1-O-caffeoyl-beta-D-glucose
|
2.4.1.7
sucrose phosphorylase
|
–
|
|
|
BRENDA:
BS407395
|
|
|
|
sucrose + caffeic_acid <=> D-fructose + caffeic_acid-3-O-alpha-D-glucopyranoside
|
2.4.1.5
dextransucrase
|
–
|
|
|
BRENDA:
BS456740
|
|
|
|
4-caffeoylquinic_acid + H2O <=> caffeic_acid + quinate
|
3.1.1.42
chlorogenate hydrolase
|
–
|
|
|
BRENDA:
BS446711
|
|
|
|
caffeic_acid + NADPH + ATP <=> caffeoyl_aldehyde + NADP+ + AMP + H2O
|
1.2.1.30
carboxylate reductase (NADP+)
|
–
|
|
|
BRENDA:
BS189197
|
|
|
|
UDP-glucose + caffeic_acid <=> UDP + 4-O-glucosyl-caffeic_acid
|
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS356095
|
|
|
|
UDP-glucose + caffeic_acid <=> UDP + caffeic_acid_4-O-beta-D-glucoside
|
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS374819
|
|
|
|
UDP-glucose + caffeic_acid <=> UDP + 1-caffeoyl-D-glucose
|
2.4.1.120
sinapate 1-glucosyltransferase
|
–
|
|
|
BRENDA:
BS378011
|
|
|
|
ethyl_caffeate + H2O <=> ethanol + caffeic_acid
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS443541
|
|
|
|
1-O-caffeoyl-beta-D-glucose + cyanidin-3-O-rutinoside <=> caffeic_acid + cyanidin_3-O-rutinoside-7-O-beta-D-glucoside
|
2.4.1.300
cyanidin 3-O-glucoside 7-O-glucosyltransferase (acyl-glucose)
|
–
|
|
|
BRENDA:
BS435376
|
|
|
|
caffeic_acid_phenethyl_ester + H2O <=> 2-phenylethanol + caffeic_acid
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS443841
|
|
|
|
3-hydroxycinnamic_acid + NADPH + H+ + O2 <=> caffeic_acid + NADP+ + H2O
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
|
|
SABIO-RK:
13540
|
|